Synthetic material does not require land space to grow crops for its production, but it emits much more CO2. Moreover, synthetic material is rarely breathable, which is bad for your skin and blood circulation. Check labels and avoid polyester (r-PET) clothes. Also, research the producer, practices they use and sustainability of the operations. Do not get lured into buying suspiciously cheap clothing – think of wok practices which you support with your purchase. 

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